Jedi Temple Archives got the numbering for the first two waves, revealing the contents of the ROTS wave:
VCP01) 4-LOM™ (C5/JediCon exclusive)
VCP02) ZUCKUSS™ (C5/JediCon exclusive)
VCP03) BOBA FETT™ (Redemption item)
VC02) CLOUD CAR PILOT™
VC03) LEIA™ (HOTH™ OUTFIT)
VC04) HAN SOLO™ (ECHO BASE™ OUTFIT)
VC05) LUKE SKYWALKER™ (BESPIN™ FATIGUES)
VC06) AT-AT COMMANDER™
VC08) DACK RALTER™
VC09) DARTH VADER™
VC10) BOBA FETT™
VC12) DARTH SIDIOUS™
VC13) ANAKIN SKYWALKER™
VC15) CLONE TROOPER™
VC16) OBI-WAN KENOBI™
VC17) GENERAL GRIEVOUS™
VC19) CLONE COMMANDER CODY™
This might be slightly off, as the AT-AT Commander's cardback was numbered #5 at Toy Fair. But it elaborates on what Hasbro said in the most recent Q&A - eight figures in the wave, seven from ROTS, one from ANH, four new ROTS figures and the rest greatest hits repacks.
We already know that we're getting Senate Duel Sidious and an updated Grievous with cape, new head, and more articulation. I assume the other new ones are Anakin (they said they're updating the 2008 figure with better elbow articulation) and Magnaguard (since the 2005 sculpt is pretty terrible, especially next to the Clone Wars versions). I doubt they're updating Obi-Wan, Cody, a clone, and a sandtrooper; they're probably just re-releasing a sandtrooper to finally get one on a vintage card.
This also reaffirms their move to release more core characters first so as not to overdose on super-obscure background guys like they have the past few years.